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I don't think so. I think you first need to transfer it onto a Orange PAYG sim card and then they will allow you to transfer it back onto a contract sim. Bit of a silly route but the only one available.
Think PAC code is only valid for 30 days or something (operator will confirm) so if you don't transfer accross in 30 days or whatever it says on your letter you remain with them until you advise that you want PAC code again.