We aren't privy to the manufacturers individual formulations (BOM's) and dosage for their finished products however all the big players (power5) BP, Shell, Total, Texaco, ESSO take the same additives. They have a base grade fuel and add our additives to make them into the premium grades e.g Shell V-power, BP ultimate etc. The supermarket brands have just the one base fuel, the standard 95RON (petrol)/51Cetane (diesel) garbage that's derived from crap quality base stocks, hence all the issues reported with supermarket fuels especially the diesel.
Tesco have the Ultimate grade which used to be the crappy supermarket base stock 95RON with an Octane booster to get the RON to 99. Now Tesco use Shell premium base stock with additional additives and octane booster to produce Momentum99, but I wouldn't be surprised if Momentum99 and V-power are exactly the same, made in the same plant just loaded onto different Tesco/Shell trucks. I've never noticed a difference between the 2 in recent years.
Ultimately all the branded 95RON/51+Cetane fuels are fine unless manufacturers recommend a higher octane grade, and I'm presuming this will just be to meet ECU parameters for extra performance and to reduce knock and ping etc, just like mapping your engine to a 99RON fuel to maximise BHP and smooth running.
STAY AWAY FROM THE 95RON/51CETANE SUPERMARKET GRADE PETROL AND DIESEL