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Register on http://forums.evo-web.co.uk and go to the patching section and option files. I've patched my PS2 PES6 game and its f*cking mint now. New balls and updated everything including stadiums etc. The PC patching is better, as there's more to patch.
Just do a search for patching guides or something like that. I have the PS2 version so its a bit different for me. You'll probably still need the same software to patch though. Makes a hell of a difference to PES6
Ahh, thats a book pack. I just go right for the boot packs which can be applied as a patch. Those ones you have to add those images into a graphic package and then install them into your game. Very clever, but too technical for me to be honest. There are so many things you can do to enhance this game. Mine now has a whole set of new boots and footballs etc. I have this patch on mine for PS2...