Don't looking at the DOT ratings for brake fluid that's only a suitability test. You want to look at the wet boiling point of the fluid if you interested in pushing the car on a track etc.
Stolen from one of the members on Frenchcarsireland:
Ive been researching brake fluids for a bit and have been written this up as a result of my findings. Its an important consumable should not be overlooked nor neglected. I'm just sharing some of what i have learned and hope its of some interest and use.I think its fairly accurate but am open to corrections should I have errors
ok
(DOT)Department of Transportation classifies brake fluids to standard specifications. These specs relate to their boiling points and chemical make-up, both of which are important. All currently available brake fluids are covered by one of the following specs DOT3, DOT4, DOT5 and DOT5.1.
Energy from braking is turned into heat through friction. A braking system only works efficiently if the fluid remains incompressible.(liquid state) If the brake fluid boils, it turns to gas, which is compressible and the braking system becomes “spongy” or in extreme cases fails completely.might as well be using compressed air to blow the pads onto the disc. As air in a hydraulic systems fluid makes it extremely inefficient.
A brake system is not perfectly sealed and moisture can get into the system and be absorbed by the fluid.(usually through time, and through a bad seal filler cap) The effect is to reduce the boiling point of the fluid, which reduces the efficiency of the braking system,
All brake fluids with the exception of silicone based fluid are hydroscopic which means that they attract water. on a side note never use a brake fluid from an open container, or one which is years old as it could be riddled with water...
and NEVER re-use old brake fluid
The D.O.T specifies two tests for brake fluids.
The dry boiling point - the boiling point of fresh brand new uncontaminated fluid
The wet boiling point is the boiling point once the fluid has absorbed water(representing brake fluid after time spent in service)
There are two main types of brake fluids:
DOT3, 4, Super4 and Dot 5.1 which are based on poly glycol composition)
Dot5 is of Silicone composition.
Note the two types of fluid are not compatible and should never be mixed in a braking system!!! (silicone based with poly glycol)
Silicone brake fluid (DOT 5)
Silicone based Dot 5 was originally introduced to give higher temperature performance over glycol Dot 4. Silicone fluid also has other advantages, it does not damage paint and it does not absorb water.(non hydroscopic)
However, silicone fluid is a poor lubricant and does not lubricate ABS pumps as well as poly glycol fluids. It is slightly more compressible than Dot3, 4, Super4 and 5.1, which can result in a sluggish or a spongy pedal.(like the feeling that you need to bleed your brakes). It does not absorb water, any water remains as blobs, which can build up in in the braking system (eg lines, abs pump etc) and cause corrosion. The water can vaporize to gas when heated under heavy braking giving a shitty effect on braking efficiency. (most lines compose of mild steel as it is more fatigue resistant to copper (which is more flexible but can age harden and crack over time)the down side for mild steel is the corrosion aspect with regards to water ingress
DOT5 fluids are not recommended for motor sport applications, and only should be used under manufacturers recommendations
Poly glycol fluids(DOT 3, 4 AND 5.1)
Glycol based DOT 4 fluid is the basic benchmark brake fluid, and has a higher boiling point both in dry and wet conditions than its predecessor.
DOT 5.1 has higher specification still and is for fast road and occasional track day use. It has a similar spec to DOT4 for the boiling point (>260) but is a lot lower viscosity @-40C typically 900 centistoke (compared to 1500 - 1800 centistoke for DOT 4 and super DOT 4).
Listed below, are the minimum dry/wet boiling point spec for each D.O.T level.
Boiling points dry and wet:
DOT 3 - 205°degrees Centigrade (dry) and 140°Degrees Centigrade (wet)
DOT 4 - 230°C (dry) and 155°C (wet)
DOT 5 (silicone) - 260°C (dry) and 185°C (wet)
DOT 5.1 (Poly glycol) - 260°C (dry) and 185°C (wet)
Super Dot4 - 300°C (dry) and 195°C (wet)
again if i have made any mistakes..... s**t this is a long post..lol