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usually as big a f number as possible (i.e. very small aperture) and also the smallest ISO number your camera will handle usually 100, to keep noise to a minimum.
Had a go at this last night, happened across a bridge over the M4 near a hotel I was staying in so I had a walk down there around 8pm. Unfortunately didn't have my remote shutter release with me so was restricted to 30 seconds, and rush hour had long gone so it was pretty quiet...