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when i had my bonnet done at locke and hankey they said that due to their method of painting and curing, the paint work can be polished straight away, to me though the paint still felt a litttle soft so i left it a week, popped a bit of wax on for a few weeks then cracked on with the machine polishers after 3 weeks
Polishing on new paint is fine - There are very few people who can get a perfect finish out of the gun, 99% of the time you freshly painted car/part will have already been polished by the time you collect it. Just make sure you use a polish without and selaants in it.