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Yeah that's a standard 24pin ATX connector, identical to what's inside a desktop PC. Never heard of that in a Clio, I'm sure someone with the knowledge will be along shortly.
I've seen these in cars before and they usually attach to a shorter harness that splits off into different connectors. Usually to power up stereos and the like. But as above I haven't come across one in the Clio's (182's) that I've owned and I've had wiring completely stripped out. It's a guess at best.
EDIT * You posted just as I was. Glad you sorted it.