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mmmm thought the a/c compressor clutch is an electromagnetic clutch as it has an electrical feed to it - press the switch and a electrical winding pulls the hub in to engaugement that the reason for the loud "click" when its switched on
are you sure its a "burning" smell - a/c systems can create a breeding ground for bacteria which makes funny smells if its not used for a while thats why they sell those canisters you let fill the interior with chemicals and put the a/c on recirculate - it draws in the chemicals to the heater matrix/heat exchanger and it this kills the bacteria - hence no smells
the compressor is in the engine bay driven by the auxillarly belt (fan belt)
I'm pretty sure its a burning smell, a bit like when you switch on a home radiator/heater after it being off a while and the dust burns. Will have another whif later though.
I have heard about the AC 'bombs' on here so might give it a go, will do no harm.