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Any decent DVD player will play DIVX/XVID files as well so providing the movie you have on you PC is in that format you can simply burn a data disc and stick it in the DVD player.
Alternatively you'll need to convert the movie to DVD (vob) format.
download and install dvd shrink from here http://www.dvdshrink.org/ that will re-encode the movie so it will fit on a 4.7gb dvd and rip the movie to your hardrive or if you got a dual layer burner and have 8.5gb dvd's you can just download and install dvd decrypter from here http://www.mrbass.org/dvdrip/ that will copy the whole movie to your hard drive then you can burn it to dvd again using nero or what ever burning software you use and it will play in your player.