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Thanks guys, this isn't my fault but a lad I know who has a 172 had his toxic fume warning light come on.
He's had it to a local Diag place and they've told him it's the knock sensor.
Although, i had RSTuner show a knock sensor fault in the 'memory', it wasnt currently present though. So he may have had a knock sensor warning at some point, and the diag he has had done has just shown it up, but it could have been in the memory for months....and not currently present...
As I understand things - the TFW light came on so he booked it in for diag.
Diag day came and the light had turned itself off again, put car on diag and it came back with a knock sensor fault.