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You can't in Outlook 2003. It would be seen as spoofing to a degree. Outlook express is the only one which allows you to select a different send From account. To do it in Outlook 2003 you would need to start up a new profile using the second account.
If you want to send from the second account you need to setup Outlook to open that mailbox. If you have send as permision for that mailbox you can send on it's behalf but the From field would show something like:
A lot of my PHP scripts spoof the "from" when sending emails.. as they are normally sent from non-accounts (if that makes sense). It incredably easy to do.
This error usually appears if the OST or PST file you are using is: · Unavailable · Protected with file permissions · On a share on a server and the network is down · Corrupt To correct this problem, store the OST or PST file on the local computer. You may also want to run the scanost.exe and scanpst.exe tools to verify file integrity. More information about this error message online.
If so when you open the other account do you use a different login to the one you normally use?
You won't be able to open a mailbox which isn't associated with your login account unless it has the relevent permissions set on the Exchange server for the account you are using to be able to access it. As I'm Admin I can just add and open any mailbox I want.
Adding that permission will only allow you to add your name in the From field when sending a mail.
To access the mailbox itself you'll need to go into Exchange Advanced and then into Mailbox rights. Just add yourself and give yourself the relevent permissions, or just sod it and add the lot. lol