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Air is 78% nitrogen anyway. 21% oxygen and 1% other gases like carbon dioxide, argon and other trace gases. Nitrogen is used alot on the continent in road tyres (i beleive) and in things like construction vehicles. Its a safety and accuracy thing. Oxygen is able to leak through rubber (very slowly) resulting in underinflation. Nitrogen cannot leak through the tyre rubber. Nitrogen also wont oxidise your wheel rims.
Yes i agree, but it depends on the compounds in the rubber. Natural rubber is permeable to alot of gases, but synthetics can be made almost impermeable to nitrogen and other gases. I beleive military aircraft have expensive rubber compounds that are impermeable to nitrogen.